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Copper Sulphate


What is copper sulphate?

Copper sulphate is an inorganic compound that combines sulfur with copper. It can kill bacteria, algae, roots, plants, snails, and fungi. The toxicity of copper sulphate depends on the copper content. Copper is an essential mineral. It can be found in the environment, foods, and water.

Why is Copper Important?

Copper is an important component of proteins found in the enzymes that regulate the rate of many biochemical reactions in plants. Plants would not grow without the presence of these specific enzymes. Research projects show that copper, promotes seed production and formation, plays an essential role in chlorophyll formation, is essential for proper enzyme activity, etc.,

Preparation of Bordeaux Mixture

Bordeaux mixture is prepared in various strengths from copper sulphate, hydrated lime (calcium hydroxide) and water. The conventional method of describing its composition is to give the weight of copper sulphate, the weight of hydrated lime and the volume of water in that order. The percentage of the weight of copper sulphate to the weight of water employed determines the concentration of the Bordeaux mixture. Thus a 1% Bordeaux mixture, which is the normal, would have the formula 1 :1:100the first 1 representing 1 kg copper sulphate, the second representing 1 kg hydrated lime, and the 100 representing 100 litres (100 kg) water. As copper sulphate contains 25% copper metal, the copper content of a 1% Bordeaux mixture would be 0-25 % copper. The quantity of lime used can be reduced considerably. Actually 1 kg copper sulphate requires only 0.225 kg of chemically pure hydrated lime to precipitate all the copper. Good proprietary brands of hydrated lime are now freely available but, as even these deteriorate on storage, it is safest not to exceed a ratio of 2:1. i.e. a 1:0.5:100 mixture. In preparing Bordeaux mixture, the copper sulphate is dissolved in half the required amount of water in a wooden or plastic vessel. The hydrated lime is mixed with the balance of the water in another vessel. The two "solutions" are then poured together through a strainer into a third vessel or spray tank.

Preparation of a 1% Burgundy Mixture

Dissolve separately 1 kg copper sulphate in 50 litres water and 125 kg washing soda (or 0.475 kg soda ash) in 50 litres water and slowly add the soda solution to the copper sulphate solution with stirring. Control of fungus diseases. Bordeaux and Burgundy mixtures have been found effective in controlling a whole host of fungus diseases of plants. Normally a 0.5 % to 1 % Bordeaux or Burgundy mixture applied at 2 to 3 week intervals suffices to control most copper-susceptible fungi. Generally once the fungus spores have alighted on the host plant and penetrated the tissues it is difficult to control them. The principle of control must in most cases depend on protection, ie preventing the fungus spores from entering the host tissues. Copper fungicides are noted for their tenacity and for this reason are much to be preferred in areas of high rainfall. The simplest method of control is to apply a protective coating of Bordeaux or Burgundy mixture (or other copper fungicide) to the susceptible parts of the plant, so that spores alighting on them come in contact with the protective film of copper and are killed instantly. It is thus important to remember that the first spraying must ideally be made just before the disease is expected and continued at intervals throughout the susceptible period. For this reason it is important to take advantage of the early warning schemes which are in operation to ensure greater accuracy of the timing of the first spraying. It must also be remembered that fungi are plants and that control measures that will kill them may not always leave the host plant unaffected. The use of too concentrated a fungicide mixture must therefore be guarded against, particularly for the early sprays. Copper fungicides have been reported effective against numerous plant diseases. A list, by no means exhaustive, of some 300 diseases that have been found amenable to control by copper fungicides

Correction of Copper Deficiency in Soils

Where copper deficiency has been confirmed by soil analysis or field diagnosis, whether in plants or animals, it can be corrected very simply either by applying 50 kg copper sulphate per hectare in the form of a fertilizer before sowing or by spraying the foliage of the young cereal plants, when they are about 150 mm high, with 750 grams copper sulphate (dissolved in from 400 to 2,000 litres water) per hectare. The soil application has generally given the better results and has the advantage that it may have a residual effect for more than ten years. The foliar application has to be given annually to each crop. An alternative is to add a copper containing slag (normally about 1% to 2 % copper) at a rate of a tonne to the hectare.

Deficiency Symptoms

In Minnesota, evidence of Cu deficiency has appeared when small grains are grown on organic soils in the northern part of the state. Symptoms of Cu deficiency are almost never seen in production fields in the remainder of the state. These deficiency symptoms are characterized by a general light green to yellow color in the small grain crop. The leaf tips die back and the tips are twisted. If Cu deficiency is severe enough, growth of small grains ceases and plants die after reaching the tillering growth stage. Wheat will not have grain in the head. Deficiency symptoms have only been observed when small grains are grown on peat soils.
• Severe copper deficiency in barley. Dieback of heads and failure of grain set
• Head deformation caused by low to deficient levels of copper particularly in later formed tillers. Mistaken for phenoxy herbicide injury in barley
• Copper deficiency in wheat is the most common cause of browning (melanosis) in wheats, particularly in the variety p. Such levels of symptoms can result in severe yield loses exceeding 75% of expected yields, not to mention quality
• Anthracnose, Leaf spot
• Grey mould, Brown eyespot
• Bitter rot